SYNTHESIS AND CHARACTERIZATION OF A NEW CATION EXCHANGER-MANGANESE (II) SILICATE DOPING WITH FE, CE, V AND W ELEMENTS AND THEIR USE FOR TREATMENT INDUSTRIAL LIQUID WASTES.

Authors

I. EL-NAGGAR, Atomic Energy Authority, Hot Labs. Center, P. No. 13759, Egypt.
E. ZAKARIA, Atomic Energy Authority, Hot Labs. Center, P. No. 13759, Egypt.
I. ALI, Atomic Energy Authority, Hot Labs. Center, P. No. 13759, Egypt.
M. EL-SABBAH, Chemistry Department, Faculty of Science, Al -Azhar University, Cairo, Egypt.
A. SOLIMAN, Chemistry Department, Faculty of Science, Al -Azhar University, Cairo, Egypt.

Corresponding Author

EL-NAGGAR, I.

Document Type

Original Article

Subject Areas

Chemistry

Keywords

CATION EXCHANGER-MANGANESE (II) SILICATE; Fe, Ce, V, W ELEMENTS

Abstract

Manganese (II) silicate has been synthesized as a gel product by direct precipitation reaction. Modifying its structure by doping with iron, cerium, vanadium and tungsten elements has been carried out. These materials were characterized using X-ray, IR ,TGA-DTA and chemical stability was studied. The prepared materials show increasing in the capacities values from 2.65, 2.55, 2.22, 1.73 and 1.50 to 3.61, 3.42, 3.11, 2.68 and 2.16 (meqg-1) for Co2+, Cd2+, Cu 2+, Cs+ and Al3+, Respectively as a result of the modification by doping. pH titration data reveal monofunctional behavior. The distribution coefficients values of metal ions have been determined at different pHs. Column application was also studied.

How to Cite This Article

EL-NAGGAR, I.; ZAKARIA, E.; ALI, I.; EL-SABBAH, M.; and SOLIMAN, A. (2010) "SYNTHESIS AND CHARACTERIZATION OF A NEW CATION EXCHANGER-MANGANESE (II) SILICATE DOPING WITH FE, CE, V AND W ELEMENTS AND THEIR USE FOR TREATMENT INDUSTRIAL LIQUID WASTES.," Al-Azhar Bulletin of Science: Vol. 21: Iss. 2, Article 26.
DOI: https://doi.org/10.21608/absb.2010.7386